Deposition of hole-transport materials in solid-state dye-sensitized solar cells by doctor-blading
نویسندگان
چکیده
We report using doctor-blading to replace conventional spin coating for the deposition of the hole-transport material spiro-OMeTAD (2,20 ,7,70-tetrakis-(N,N-di-p-methoxyphenylamine)-9,90-spirobifluorene) in solid-state dye-sensitized solar cells. Doctor-blading is a roll-to-roll compatible, large-area coating technique, is capable of achieving the same spiro-OMeTAD pore filling fraction as spin coating, and uses much less material. The average power conversion efficiency of solid-state dye-sensitized solar cells made from doctorblading is 3.0% for 2-lm thick films and 2.0% for 5-lm thick films, on par with devices made with spin coating. Directions to further improve the filling fraction are also
منابع مشابه
11% efficiency solid-state dye-sensitized solar cells with copper(II/I) hole transport materials
Solid-state dye-sensitized solar cells currently suffer from issues such as inadequate nanopore filling, low conductivity and crystallization of hole-transport materials infiltrated in the mesoscopic TiO2 scaffolds, leading to low performances. Here we report a record 11% stable solid-state dye-sensitized solar cell under standard air mass 1.5 global using a hole-transport material composed of ...
متن کاملElectron Transfer in Dye-Sensitized Nanocrystalline TiO2 Solar Cell
The dye-sensitized solar cells (DSSC) have been regarded as one of the most promising new generation solar cells. Tremendous research efforts have been invested to improve the efficiency of solar energy conversion which is generally determined by the light harvesting efficiency, electron injection efficiency and undesirable electron lifetime. In this review, various characteristics of dye-...
متن کاملContribution from a hole-conducting dye to the photocurrent in solid-state dye-sensitized solar cells.
The hole transporting medium in solid-state dye-sensitized solar cells can be utilized to harvest sunlight. Herein we demonstrate that a triphenylamine-based dye, used as hole-transporting medium, contributes to the photocurrent in a squaraine-sensitized solid-state dye-sensitized solar cell. Steady-state photoluminescence measurements have been used to distinguish between electron transfer and...
متن کاملEnhancing the hole-conductivity of spiro-OMeTAD without oxygen or lithium salts by using spiro(TFSI)₂ in perovskite and dye-sensitized solar cells.
2,2',7,7'-Tetrakis(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD), the prevalent organic hole transport material used in solid-state dye-sensitized solar cells and perovskite-absorber solar cells, relies on an uncontrolled oxidative process to reach appreciable conductivity. This work presents the use of a dicationic salt of spiro-OMeTAD, named spiro(TFSI)2, as a facile means ...
متن کاملThe influence of 1D, meso- and crystal structures on charge transport and recombination in solid-state dye-sensitized solar cells
We have prepared single crystalline SnO2 and ZnO nanowires and polycrystalline TiO2 nanotubes (1D networks) as well as nanoparticle-based films (3D networks) from the same materials to be used as photoanodes for solid-state dye-sensitized solar cells. In general, superior photovoltaic performance can be achieved from devices based on 3-dimensional networks, mostly due to their higher short circ...
متن کامل